The application of thermal analysis techniques is based on either thermodynamic considerations or the kinetics of change. It is not just the fact that the temperature is being changed that makes a choice of this kind necessary, but the kind of systems investigated. Some macromolecules are so big that phase changes which, in simple systems, would show only thermodynamic (equilibrium) features exhibit a kinetic factor. In the preceding survey certain techniques have not been reported or have not been described in detail. Only the main techniques available from more than one commercial manufacturer have been reported in some detail.

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